Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. However, molybdenum itself does not get incorporated in the passive film. The most common forms of corrosion in stainless steel are. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Nuregcr7030, atmospheric stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless. Therefore, standard grades such as 304304l and 316316l are very susceptible to this mode of attack. Stresscorrosion cracking data generated by autoclave tests agreed well with. Written especially for design engineers, it presents an overview of a broad range of stainless steels both standard and proprietary their compositions. I have been reading into stress corrosion cracking scc caused by chlorides, which i understand can be quite an issue. F kjkg it has superior chloride stress corrosion cracking resistance to types 304 and 316.
Corrosion resistance of ferritic stainless steels total. Aisi 304 stainless steel ss is one of the candidate materials used for dry storage. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Samples were subject to 60 mpa stress, 90 c at 70% relative humidity, for 480 h.
How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stress corrosion cracking of an austenitic stainless steel in. To provide more complete data on the performance of stainless steels in underground applications, including data on many different soil conditions, the committee of stainless steel producers initiated an extended test program in cooperation with the national bureau of standards. Ferritic stainless steels have certain useful corrosion properties, such as resistance to chloride stress corrosion cracking, corrosion in oxidizing aqueous media, oxidation at high temperatures and pitting and crevice corrosion in chloride media. Stress corrosion of type 304 stainless steel in chloride. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Grade 304 stainless steel is excellent in a wide range of atmospheric environments and many corrosive media.
Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Chloride stress corrosion cracking scc of type 304 and 304l austenitic. The chloride stresscorrosion cracking behavior of stainless steels. Stainless steel corrosion data from just manufacturing. What is the maximum chloride in ppm that can be allowed in. Preventing stress corrosion cracking of austenitic stainless steels in chemical plants. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Stress corrosion cracking of type aisi 304 stainless steel at. Pitting corrosion crevice corrosion stress corrosion cracking pitting corrosion tends to be associated with free surfaces of stainless steel. The 304 austenitic stainless steel was experimented in acid hydrogen chloride aqueous solution with mixing ratio 1. As the name implies, localized corrosion affects only specific local areas rather than the broad surface of the metal. Reference is often made to stainless steel in the singular sense as if it were one material. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
Corrosion of stainless steels in supply drinking and. This paper presents a fusion welding process that was developed for snf canister repair. There are three main types of localised corrosion mechanisms that can affect stainless steels. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The ability of stainless steels to resist corrosion is related to the chromium content, for chromium is the alloying element that endows stainless steels with their corrosion resistance. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Chloride stress corrosion cracking and 316 stainless steel chloride stress corrosion cracking and 316 stainless steel beh188 mechanical op 19 jul 11 17. Pitting corrosion and stress corrosion cracking of.
A strain rate of 5 x 10sup 4 minutesup 1 was employed. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions l. Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride. Chloride induced stress corrosion cracking of type 304 and. Stress corrosion cracking of type aisi 304 stainless steel. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Hydrochloric acid and sulphuric acid at some concentrations are particular aggressive towards stainless steel. With stainless steel it takes the form of pitting, crevice corrosion and stress corrosion cracking scc. Stainless steels are more resistant to general corrosion compared with carbon steel. Austenitic type 304 uns s30400 stainless steel is susceptible to stress corrosion cracking scc in acidic chloride cl. Specifications ak steel type 444 stainless steel sheet and strip is covered by the following specifications.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Therefore, standard grades such as 304304l and 316 316l are very susceptible to this mode of attack. In general, austenitic stainless steels are subject to chloride stress corrosion cracking in halide service. Scc caused by chlorides and examining what causes scc and. To fill this need, the committee of stainless steel producers initially prepared this booklet. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Type 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. The standard 304 304l and 316316l grades are most susceptible. Design guidelines for the selection and use of stainless steel nidl distributed by. The effect of salt loading on chloride induced stress corrosion cracking in 304 l was studied at atmospheric pressure. Summary of available data for estimating chlorideinduced scc crack growth rates for. Nickel and copper residuals lower resistance of these steels to stress corosion.
Film and ph effects in the stress corrosion cracking of. Stainless steel gains its ability to resist corrosion by forming a passive layer on its surface. Ferritic steels resist chloride and caustic stress corrosion cracking very well. External applied stress by ubending was also applied to specimen in order to further study stress corrosion cracking phenomenon.
Neutral chloride solutions also cause some cracking at room temperature, particularly if a thick oxide is grown. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Chloride stress corrosion cracking in austenitic stainless steel. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Summary of available data for estimating chlorideinduced scc. Highly alloyed austenitic stainless steels s32654, s31254. The time to failure at a constant stress, chloride ion concentration. Austenitic stainless steels may be susceptible to chloride stress corrosion cracking cscc.
To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. Stress corrosion cracking in a brewery paul mueller company. Corrosion of stainless steels in supply drinking and waste. Pdf chloride induced stress corrosion cracking of type 304 and. Effects of marine environments on stress corrosion cracking. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated. Stresscorrosion cracking of sensitized type 304 stainless. Specifications type 444 stainless steel sheet and strip is covered by the following.
Isaacs the stress corrosion cracking of a sensitized type 304 stainless steel has been studied at room. Torchio laboratory of electrochemistry and metallurgy, university of milan, via g. Considered resistant to potable water with up to about. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature.
Influence of high temperature on corrosion behavior of 304. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. A film of more acidic corrodent solution is raised to ph 1. It has superior chloride stress corrosion cracking resistance to types 304 and 316. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This mode of attack is termed stress corrosion cracking scc.
Although no stainless steel grade is totally immune. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Higher levels of chloride might cause crevice corrosion and pitting. Ak steel 444 is equivalent to type 304 in many corrosion environments and has lower coefficient of expansion and better thermal conductivity. Film and ph effects in the stress corrosion cracking of type. The investigation of austenitic stainless steel attacked by acid chloride containing environment was done. Stress corrosion cracking of austenitic type 304 stainless. Chloride stress corrosion cracking inspectioneering. Physical properties of 304 grade stainless steel in the annealed condition. Rapid stress corrosion cracking of 304 stainless steel in mgcl 2fecl 3 solutions at 125 c has been shown to occur only when the ph of the corrodent liquid within the crack lay between 1.
Stresscorrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Methods of minimizing chloride stress corrosion cracking. The type 302, 304, 304l and 305 alloys are the most susceptible of the austenitic stainless steels to stress corrosion cracking in halides because of their relatively low nickel content. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. Stress corrosion cracking susceptibility of 304l substrate. Resistance to stresscorrosion cracking is the most obvious advantage of the ferritic stainless steels.
Stress corrosion cracking facts and how to reduce the risk. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stress corrosion cracking facts and how to reduce the. Conventional stainless steels such as 304l and 316l are susceptible to chloride stress corrosion cracking ssc under certain conditions. Duplex grades are usually divided into three subgroups based on their corrosion resistance. Chloride stress corrosion cracking the hendrix group. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm.
Stress corrosion cracking of an austenitic stainless steel. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. This together with slightly higher stacking fault energy schramm and reed 1975 are the main reasons for better resistance of type 316316l stainless steel than type 304 304l to stress corrosion cracking in sodium chloride solutions. Conditions which cause stress corrosion cracking are.
What forms of corrosion can occur in stainless steels. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Type 304 stainless steel an overview sciencedirect topics. Sensor requirements for detection and characterization of. Chloride induced stress corrosion cracking of type 304. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework. Deterioration by clscc can lead to failures that have the potential to release. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. In this study, a layer of adsorbed product film enriched in chromium and nickel was found to form on the metal surface in the solutions.
The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. It is subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above 60 c approximate. Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Pdf chloride stress corrosion cracking scc of type 304 and. Type 316 is more resistant to corrosion that type 304, especially chlorides pitting attack.
Chloride stress corrosion cracking and 316 stainless steel. Influence of high temperature on corrosion behavior of 304 stainless steel in chloride solutions aip advances. Stress corrosion cracking of sensitized type 304 stainless. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Masami mayuzumi, taku arai and koichiro hide central research institute of electric power industry chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of 35%. The effect of salt loading on chlorideinduced stress. The stress corrossion behavior of aisi type 304 stainless steel was investigated as a function of the environmental variables, temperature, ph, cation species, and chloride concentration in concentrated solutions of mgcl 2, cacl 2 and licl.
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